Sorption of americium by detonation synthesis nanodiamonds from aqueous solutions of various compositions

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

Sorption of americium by commercial samples of detonation nanodiamonds (NDs) from nitric acid, neutral, and alkaline solutions was investigated. Sorption kinetics and dependence of sorption degree on pH, ionic strength, m/V ratio and temperature were studied. Thermodynamic parameters of americium adsorption by NDs were determined for the first time. Conditions of quantitative sorption of americium by NDs samples were found; it was shown that NDs are promising sorbents for decontamination of natural waters from possible americium impurities.

Негізгі сөздер

Толық мәтін

Рұқсат жабық

Авторлар туралы

А. Kazakov

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS

Хат алмасуға жауапты Автор.
Email: kazakov.ag@geokhi.ru
Ресей, ul. Kosygina 19, Moscow, 119991

D. Pavlova

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS; Mendeleev Russian University of Chemical Technology

Email: kazakov.ag@geokhi.ru
Ресей, ul. Kosygina 19, Moscow, 119991; Miusskaya pl. 9, Moscow, 125047

S. Vinokurov

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS

Email: kazakov.ag@geokhi.ru
Ресей, ul. Kosygina 19, Moscow, 119991

B. Myasoedov

Vernadsky Institute of Geochemistry and Analytical Chemistry, RAS; Interdepartmental Center for Analytical Research in Physics, Chemistry, and Biology, RAS

Email: kazakov.ag@geokhi.ru
Ресей, ul. Kosygina 19, Moscow, 119991; Moscow, 117997

Әдебиет тізімі

  1. Khvorostinin E.Y., Osin P.A., Trofimov T.I., Kulyako Y.M., Vinokurov S.E. // At. Energy. 2023. Vol. 134. P. 338–345.
  2. Runde W.H., Mincher B.J. // Chem. Rev. 2011. Vol. 111. N 9. P. 5723–5741.
  3. Magill J., Berthou V., Haas D., Galy J., Schenkel R., Wiese H.W. et al. // Nucl. Energy. 2003. Vol. 42. N 5. P. 263.
  4. Evsiunina M.V., Matveev P.I., Kalmykov S.N., Petrov V.G. // Moscow Univ. Chem. Bull. 2021. Vol. 76. P. 287–315.
  5. Matveev P.I., Mohapatra P.K., Kalmykov S.N., Petrov V.G. // Solvent Extr. Ion Exch. 2020. Vol. 39. N 7. P. 679–713.
  6. Holm E., Roos P., Aarkrog A.A., Mitchell A., Vintro L.L. // J. Radioanal. Nucl. Chem. 2002. Vol. 252. P. 211–214.
  7. Buchatskaya Y., Romanchuk A., Yakovlev R., Shiryaev A., Kulakova I., Kalmykov S. // Radiochim. Acta. 2015. Vol. 103. N 3. P. 205–211.
  8. Kazakov A.G., Garashchenko B.L., Yakovlev R.Y., Vinokurov S.E., Kalmykov S.N., Myasoedov B.F. // Diam. Relat. Mater. 2020. Vol. 104. ID 107752.
  9. Kazakov A.G., Garashchenko B.L., Yakovlev R.Y., Vinokurov S.E., Myasoedov B.F. // Radiochemistry. 2020. Vol. 62. P. 752–758.
  10. Kazakov A.G., Babenya J.S., Ivanova M.K., Vinokurov S.E., Myasoedov B.F. // Radiochemistry. 2022. Vol. 64. P. 44–48.
  11. Babenya J.S., Kazakov A.G., Ekatova T.Y., Yakovlev R.Y. // J. Radioanal. Nucl. Chem. 2021. Vol. 329. N 2. P. 1027–1031.
  12. Kazakov A.G., Garashchenko B.L., Ivanova M.K., Vinokurov S.E., Myasoedov B.F. // Nanomaterials. 2020. Vol. 10. N 6. ID 1090.
  13. Kazakov A.G., Garashchenko B.L., Babenya J.S., Ivanova M.K., Vinokurov S.E., Myasoedov B.F. // RAD Conf. Proc. 2020. Vol. 4. P. 1–6.
  14. Kazakov A.G., Garashchenko B.L., Yakovlev R.Y., Vinokurov S.E., Kalmykov S.N., Myasoedov B.F. // Radiochemistry. 2020. Vol. 62. P. 592–598.
  15. Kazakov A.G., Babenya J.S., Ekatova T.Y., Vinokurov S.E., Myasoedov B.F. // Adv. Geochem., Anal. Chem. Planet. Sci. 2023. P. 595–601.
  16. Garashchenko B.L., Dogadkin N.N., Borisova N.E., Yakovlev R.Y. // J. Radioanal. Nucl. Chem. 2018. Vol. 318. P. 2415–2423.
  17. Kazakov A.G., Babenya J.S., Ekatova T.Y., Vinokurov S.E., Khvorostinin E.Y., Ushakov I.A. et al. // Radiochemistry. 2024. Vol. 66. N 2. P. 191–197.
  18. Kazakov A.G., Babenya J.S., Ekatova T.Y., Vinokurov S.E., Khvorostinin E.Y., Ushakov I.A. et al. // Radiochemistry. 2024. Vol. 66. N 2. P. 198–204.
  19. Kazakov A.G., Ekatova T.Y., Vinokurov S.E., Khvorostinin E.Y., Ushakov I.A., Zukau V.V. et al. // Radiochemistry. 2024. Vol. 66. N 2. P. 205–210.
  20. Karmanov A.P., Dolmatov V.Y., Kocheva L.S., Rachkova N.G., Bogdanovich N.I., Almazova N.S. // J. Superhard Mater. 2021. Vol. 43. P. 203–212.
  21. Volkov D.S., Krivoshein P.K., Mikheev I.V., Proskurnin M.A. // Diam. Relat. Mater. 2020. Vol. 110. ID 108121.
  22. Ahmadijokani F., Molavi H., Peyghambari A., Shojaei A., Rezakazemi M., Aminabhavi T.M., Arjmand M. // J. Environ. Manag. 2022. Vol. 316. ID 115214.
  23. Sakurai H., Ebihara N., Ōsawa E., Takahashi M., Fujinami M., Oguma K. // Anal. Sci. 2006. Vol. 22. P. 357–362.
  24. Peristyy A., Paull B., Nesterenko P.N. // Adsorption. 2016. Vol. 22. P. 371–383.
  25. Baghban N., Yilmaz E., Soylak M. // J. Mol. Liq. 2017. Vol. 234. P. 260–267.
  26. Soylak M., Aksu B., Hassan E., Hassan A. // Food Chem. 2024. Vol. 445. ID 138733.
  27. Nesterenko P.N., Fedyanina O.N., Volgin Y.V., Jones P. // J. Chromatogr. A. 2007. Vol. 1155. N 1. P. 2–7.
  28. Schönherr J., Buchheim J.R., Scholz P., Adelhelm P. // C. 2018. Vol. 4. P. 21.
  29. Oickle A.M., Goertzen S.L., Hopper K.R., Abdalla Y.O., Andreas H.A. // Carbon. 2010. Vol. 48. N 12. P. 3313–3322.
  30. Kalam S., Abu-Khamsin S.A., Kamal M.S., Patil S. // ACS Omega. 2021. Vol. 48. N 6. P. 32342–32348. https://doi.org/10.1021/acsomega.1c04661
  31. Biggar J.W., Cheung M.W. // Soil Sci. Soc. Am. J. 1973. Vol. 37. N 6. P. 863–868.
  32. Niwas R., Gupta U., Khan A.A., Varshney K.G. // Colloids Surf. A: Physicochem. Eng. Aspects. 2000. Vol. 164. N 2–3. P. 115–119.
  33. https://doi.org/10.1016/S0927-7757(99)00247-2
  34. Crini G., Badot P.M. // Prog. Polym. Sci. 2008. Vol. 33. N 4. P. 399–447.
  35. Kazakov A.G., Pavlova D.V., Ushakov I.A., Nesterov E.A., Skuridin V.S., Odintsova E.A. et al. // Radiochemistry. 2024. Vol. 66. N 6. P. 865–871.

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML
Жүктеу
2. Fig. 1. Dependence of the ζ-potential of the surface of TAN and STP aggregates on pH.

Жүктеу (59KB)
Метадеректер
3. Fig. 2. Kinetics of americium sorption in media with pH from 3 to 10 by TAN (a) and STP (b) samples at 25°C; HA content 100 μg/ml.

Жүктеу (168KB)
Метадеректер
4. Fig. 3. Dependence of the degree of americium sorption on pH and salt background at an HA content of 100 μg/ml at 25°C.

Жүктеу (191KB)
Метадеректер
5. Fig. 4. Dependence of the degree of americium sorption at different pH on the NA content at 25°C.

Жүктеу (149KB)
Метадеректер
6. Fig. 5. Effect of temperature on the degree of americium sorption by the TAN sample at pH 6 with different NA contents.

Жүктеу (78KB)
Метадеректер
7. Fig. 6. Approximation of experimental data (points) by the Henry isotherm model (lines) for the sorption of americium by the TAN sample at pH 6.

Жүктеу (87KB)
Метадеректер

© Russian Academy of Sciences, 2025