Features of the Structure of 2,5-Dimercapto-1,3,4-Thiadiazole

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Resumo

For the first time, using quantum chemical analysis, the structure of 2,5-dimercapto-1,3,4-thiadiazole was proposed, which is described by a single formula in the form of three putative isomers, which is a crystalline tribasic RS–H Brensted acid formed solely by hydrogen bonds involving four nitrogen atoms and three sulfur atoms, which is confirmed by X-ray diffraction analysis and FTIR spectra. These structural features must be considered in the production technology of the target product.

Sobre autores

T. Aleinikova

Volgograd State Technical University

Email: aleynikova_tp@vstu.ru
400005 Volgograd, Russian Federation

V. Orlyanskii

Scientific and production enterprise "KF"

404117 Volzhsky, Volgograd region, Russian Federation

V. Arisova

Volgograd State Technical University

400005 Volgograd, Russian Federation

V. Navrotskii

Volgograd State Technical University

400005 Volgograd, Russian Federation

I. Novakov

Volgograd State Technical University

400005 Volgograd, Russian Federation

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