Synthesis and Crystal Structure of Cobalt Complexes with Cucurbit[6]uril

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Four cobalt complexes with cucurbit[6]uril (CB[6]), [Co(H2O)6](Bdc) · CB[6] · 14.5H2O (I), 2(H2NMe2)2[CoCl4] · CB[6] ·12H2O (II), [{Co(H2O)4Cl}4(CB[6])]Cl4 · 9H2O (III) and [Co(H2O)6]-[Co(H2O)5(Dmf)][CoCl4]2 · CB[6] · 6H2O (IV), were prepared by evaporation of the reaction solution containing cobalt chloride and cucurbit[6]uril (CB[6]). According to X-ray diffraction data, compound I is formed by packing of cationic cobalt aqua complexes, terephthalate anions, and CB[6] molecules linked together by hydrogen bonds with crystallization water molecules into a supramolecular cage. The structure of compound II represents a packing of CB[6] molecules, dimethylammonium cations, and anionic cobalt chloro complexes. Compound III contains tetranuclear cationic cobalt chloro aqua complexes with CB[6], with chloride anions acting as counter-ions. The crystal structure of IV is a packing of cationic cobalt aqua complexes, anionic cobalt chloro complexes, and CB[6] molecules linked by hydrogen bonds with crystallization water molecules into a supramolecular cage. The resulting compounds are characterized by IR spectra and elemental analysis data.

作者简介

I. Andrienko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia

D. Samsonenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia

E. Kovalenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: e.a.kovalenko@niic.nsc.ru
Novosibirsk, Russia

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